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- W2079663061 abstract "It is attempted to describe the solid state of linear crystalline polymers using the defect concept. This metastable solid state which is normally found in polymers is described thermodynamically. Changes in state are traced as a function of heating rate. The limiting experimental maximum melting point on fast heating, Tm, is described by the equation InXA=HuR(T−3m—Tm−1) which contains as parameters the activity of crystallizable units in the melt, XA, the heat of fusion at Tm, ΔHu, and the experimental maximum melting point on fast heating of large defect free lamellae into a melt XA = 1:Tfm. For linear polyethylene experimental evidence is cited which supports the theoretical description." @default.
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- W2079663061 date "1964-01-01" @default.
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- W2079663061 title "A thermodynamic description of the defect solid state of linear high polymers" @default.
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