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• W2079665467 abstract "The synthesis and single-crystal X-ray structure of an ion-pair complex, [4,4′-H2bpy][Cu(mnt)2] (1), is described. In the crystal structure, the interactions between anions and cations via bifurcated (bpyN)–H⋯(NC–mnt)2 hydrogen bonds give rise to a three-dimensional supramolecular network having well-defined channels. Complex 1 exhibits two redox waves at +0.44 and −0.36 V (versus SCE) in dimethylformamide corresponding to the Cu(mnt)2]1−/Cu(mnt)2]2− and [4,4′-H2bpy]2+/[4,4′-H2bpy]1+ couples, respectively. The near-IR absorption at 1225 nm in the solid state has been attributed to the charge transfer from the copper dithiolate anion, [Cu(mnt)2]2−, to the bipyridinium cation, [4,4′-H2bpy]2+." @default.
• W2079665467 created "2016-06-24" @default.
• W2079665467 creator A5063914491 @default.
• W2079665467 creator A5070564138 @default.
• W2079665467 date "2004-04-01" @default.
• W2079665467 modified "2023-09-23" @default.
• W2079665467 title "Near-IR absorption due to supramolecular electronic interaction in an extended 3D hydrogen-bonding network material: synthesis, crystal structure and properties of [4,4′-H2bpy][Cu(mnt)2]" @default.
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• W2079665467 doi "https://doi.org/10.1016/j.poly.2004.02.002" @default.
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