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• W2079666988 startingPage "295" @default.
• W2079666988 abstract "The photocatalytic degradation of the four acids ClxCH3-xCOOH (x = 0–3) in the presence of UV-irradiated TiO2 was studied under O2, N2 and N2O. The formation of CO2, Cl− and CH2O with time was monitored. The decomposition rate depends strongly on the value of x and on the gas under which the reaction takes place. It is much higher under O2 than under N2O if hydrogen is bound to the α-carbon atom of the acid. The fast reaction under O2 is inhibited by addition of H2O2. Information on the nature of the intermediate free radicals was obtained from spin-trap experiments. Mechanisms involving several reactive species are deduced from the differences in reactivity of the acids." @default.
• W2079666988 created "2016-06-24" @default.
• W2079666988 creator A5019627029 @default.
• W2079666988 creator A5031858484 @default.
• W2079666988 date "1990-07-01" @default.
• W2079666988 modified "2023-10-12" @default.
• W2079666988 title "A study of the primary step in the photochemical degradation of acetic acid and chloroacetic acids on a TiO2 photocatalyst" @default.
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• W2079666988 doi "https://doi.org/10.1016/0304-5102(90)85253-e" @default.
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