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- W2079673500 abstract "The assumption of a random distribution of chalcogen atoms in the wurtzite structure is usually made to interpret the properties of ternary CdSxSe1-x compounds. However, there has not yet been any experimental evaluation of this distribution. The authors report here the results of low-temperature X-ray absorption measurements (4.5 K) at the selenium K edge in CdSxSe1-x compounds for x=0, 0.2, 0.5 and 0.8. These measurements make a quantitative analysis of the next-nearest neighbours up to the fourth-neighbour shell around selenium atoms possible. The numbers of sulphur and selenium second neighbours of selenium atoms for each ternary compound are found to be proportional to the respective molar ratio. The analysis can be made with the best accuracy for x=0.5, and no clustering is observed. As maximum clustering is expected for this value of x, it is concluded that derivation from the random distribution of selenium atoms is very small in CdSxSe1-x." @default.
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- W2079673500 date "1993-05-31" @default.
- W2079673500 modified "2023-09-30" @default.
- W2079673500 title "Distribution of chalcogen atoms in the wurtzite CdSxSe1-xsolid solution: experimental study by X-ray absorption" @default.
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- W2079673500 doi "https://doi.org/10.1088/0953-8984/5/22/004" @default.
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