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- W2079706674 abstract "The kinetics of general base catalyzed proton exchange in N,N′-dimethylurea and a series of secondary amides were studied. Kinetic data were determined by NMR line-shape analysis. A good linear correlation was observed for nine amides by plotting log kOH for RCONHCH3 vs. pKa of RCOOH. For amides with N–H more acidic than water (pKa < 15.7), general base catalysis is observed, the Bronsted β is unity, and the reaction with hydroxide is diffusion-controlled. It is concluded that general base catalysis is inoperative in proteins or polypeptides." @default.
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- W2079706674 date "1994-04-01" @default.
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- W2079706674 title "General Base Catalyzed Proton Exchange in Amides" @default.
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- W2079706674 doi "https://doi.org/10.1246/bcsj.67.1054" @default.
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