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- W2079717768 abstract "Based on a donor–acceptor framework, several conjugates have been designed and prepared in which an electron-donor moiety, ytterbium(III) porphyrinate (YbPor), was linked through an ethynyl bridge to an electron-acceptor moiety, boron dipyrromethene (BODIPY). Photoluminescence studies demonstrated efficient energy transfer from the BODIPY moiety to the YbPor counterpart. When conjugated with the YbPor moiety, the BODIPY moiety served as an antenna to harvest the lower-energy visible light, subsequently transferring its energy to the YbPor counterpart, and, consequently, sensitizing the YbIII emission in the near-infrared (NIR) region with a quantum efficiency of up to 0.73 % and a lifetime of around 40 μs. Moreover, these conjugates exhibited large two-photon-absorption cross-sections that ranged from 1048–2226 GM and strong two-photon-induced NIR emission." @default.
- W2079717768 created "2016-06-24" @default.
- W2079717768 creator A5027225358 @default.
- W2079717768 creator A5035701638 @default.
- W2079717768 creator A5075050169 @default.
- W2079717768 creator A5090859686 @default.
- W2079717768 date "2012-11-20" @default.
- W2079717768 modified "2023-10-17" @default.
- W2079717768 title "Light-Harvesting Ytterbium(III)-Porphyrinate-BODIPY Conjugates: Synthesis, Excitation-Energy Transfer, and Two-Photon-Induced Near-Infrared-Emission Studies" @default.
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- W2079717768 doi "https://doi.org/10.1002/chem.201202613" @default.
- W2079717768 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23165692" @default.
- W2079717768 hasPublicationYear "2012" @default.
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