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- W2079718206 abstract "In order to shed light on the stereoselectivity of acetonitrile-mediated glycoslation reactions, the nitrilium intermediates have been genegrated at —30°C in acetonintrile-d3 and studied by 1H, 13C, and 15N NMR spectroscopy. Conjointly, molecular modeling of the intermediates by molecular mechanics has been performed with the CHARMm force field. All the evidence suggests that only nitrilium derivatives with the α configuration are formed." @default.
- W2079718206 created "2016-06-24" @default.
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- W2079718206 date "1993-08-01" @default.
- W2079718206 modified "2023-09-30" @default.
- W2079718206 title "Conformational analysis of nitrilium intermediates in glycosylation reactions" @default.
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- W2079718206 doi "https://doi.org/10.1016/0008-6215(93)84021-w" @default.
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