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- W2079723943 abstract "The carbanilides Triclocarban (TCC), [N-(4-chlorophenyl)-N′-(3,4-dichlorophenyl)urea] (101-20-2) and Halocarban, (HC), (N-[4-chlorophenyl]-N′-[4-chloro-3-(trifluoromethyl)phenyl]urea) (369-77-7) are used in deodorant soaps because of their bacteriostatic properties. In order to relate the rates of hydrolysis of TCC and HC with the structure of these substituted ureas, comparative hydrolysis studies have been made with these compounds, as well as phenylurea (64-10-8), 4-chlorophenylurea (140-38-5), diphenylurea (102-07-8), N-(4-chlorophenyl)-N′-phenylurea (140-38-5) and N,N′bis (4-chlorophenylurea (1219-99-4). Pseudo first-order rate constants at 25°C for hydrolysis in 0.5 M NaOH (in 77% ethanol-23% water, by vol) varied from 2 × 10−4 to 9 × 10−4 day−1, yielding corresponding half-lives between 2 and 10 yr, respectively. Activation energies have been calculated. For the first two compounds extrapolation to pure water solutions have been made." @default.
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- W2079723943 date "1988-09-01" @default.
- W2079723943 modified "2023-10-18" @default.
- W2079723943 title "Comparative hydrolysis of substituted ureas in a mixed alcoholic-water solution" @default.
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- W2079723943 doi "https://doi.org/10.1016/0043-1354(88)90011-5" @default.
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