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• W2079724829 abstract "Abstract The phase stability of SrCo0.8Fe0.2O3−d perovskite doped with niobium was studied by in situ high-temperature X-ray diffraction in the temperature range of 30–1000 °C and oxygen partial pressure 0.2–10−5 atm. The stability of the cubic perovskite structure in a wide range of oxygen partial pressures is the main advantage of SrCo0.8−xFe0.2NbxO3−d (x = 0.1–0.3) system in comparison with SrCo0.8Fe0.2O3−d. It is suggested that equilibrium of the thermal expansion with changes of the oxygen non-stoichiometry leading to the same lattice parameters in the oxidizing and reducing environments at the catalytic temperatures is a necessary requirement for stable operation of perovskite as an oxygen-conducting membrane. In the case of SrCo0.8−xFe0.2NbxO3−d perovskite this condition is met at x = 0.2. This makes the SrCo0.6Fe0.2Nb0.2O3−d composition promising for application as oxygen-conducting membrane." @default.
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• W2079724829 date "2009-10-01" @default.
• W2079724829 modified "2023-09-26" @default.
• W2079724829 title "Properties of Nb-doped SrCo0.8Fe0.2O3−d perovskites in oxidizing and reducing environments" @default.
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• W2079724829 doi "https://doi.org/10.1016/j.cattod.2009.01.017" @default.
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