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• W2079724906 endingPage "1963" @default.
• W2079724906 startingPage "1956" @default.
• W2079724906 abstract "A Pd-catalyzed aerobic oxidative C–H nitration and acylation of arenes with simple and readily available tert-butyl nitrite (TBN) and toluene as the radical precursors has been developed. Molecular oxygen is employed as the terminal oxidant and oxygen source to initiate the active radical reactants. Many different directing groups such as pyridine, pyrimidine, pyrazole, pyridol, pyridylketone, oxime, and azo groups can be employed in these novel transformations. The PdII/PdIV catalytic cycle through a radical process is the most likely pathway for these oxidative C–H nitration and acylation reactions." @default.
• W2079724906 created "2016-06-24" @default.
• W2079724906 creator A5011355109 @default.
• W2079724906 creator A5011833760 @default.
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• W2079724906 creator A5041322321 @default.
• W2079724906 creator A5047717116 @default.
• W2079724906 creator A5088203711 @default.
• W2079724906 date "2015-02-24" @default.
• W2079724906 modified "2023-10-15" @default.
• W2079724906 title "Aerobic Oxidation of Pd^II to Pd^IV by Active Radical Reactants: Direct C–H Nitration and Acylation of Arenes via Oxygenation Process with Molecular Oxygen" @default.
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