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- W2079725887 abstract "A new 3d–4f bimetallic coordination polymer {[Ce2Cu3(oda)6 (H2O)3]·4H2O}n (1) (H2oda = oxydiacetic acid) has been hydrothremally synthesized and structurally characterized by single-crystal X-ray diffraction, elemental analyses, magnetism, fluorescence, and EPR spectroscopies. The compound crystallizes in hexagonal crystal system, space group P-62c (no. 190). In 1, the Ce3+ ion is nine coordinated with six carboxylate O atoms and three ether O atoms from three oxydiacetate (oda2−) ligands in a tricapped trigonal prismatic geometry, while the Cu2+ ion is five coordinated by the remaining outer carboxylate O atoms from four oda2− and one aqua ligand in a distorted square-pyramid configuration. The Ce3+ ions and Cu2+ ions are connected by the carboxyl groups of the oda2−, thus leading to the formation of a highly ordered 3D hexagonal channel frameworks. The photoluminescent, EPR, and magnetic properties of the title complex also have been investigated." @default.
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- W2079725887 date "2013-11-06" @default.
- W2079725887 modified "2023-10-12" @default.
- W2079725887 title "A Heterometallic Copper(II)-Cerium(III) Complex Bridged by Oxydiacetate Ligand: Synthesis, Structure, Spectral, and Magnetic Properties of {[Ce<sub>2</sub>Cu<sub>3</sub>(oda)<sub>6</sub>(H<sub>2</sub>O)<sub>3</sub>]·4H<sub>2</sub>O}<sub>n</sub>" @default.
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- W2079725887 doi "https://doi.org/10.1080/15533174.2013.769588" @default.
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