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• W2079733727 abstract "The solid solution of (x)Ba0.7Ca0.3TiO3-(1-x)BaZr0.2Ti0.8O3 is known to exhibit high piezoelectric constants. Discrepancies in the reported phase transitions and structure around room temperature, however, have complicated the understanding of the enhanced properties. Rietveld refinement of high-resolution X-ray diffraction is employed here to establish and refine the crystallographic structure at temperatures from −100 °C to 150 °C for x = 0.5. A combination of rhombohedral R3m and tetragonal P4mm is found to coexist at temperatures of 20 °C and −25 °C, bordered by single phase rhombohedral and tetragonal regions at lower (i.e., −100 °C) and higher (i.e., 70 °C) temperatures, respectively. The diffractograms also show signs of strain and domain wall scattering that are linked to the sample history." @default.
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• W2079733727 date "2013-01-03" @default.
• W2079733727 modified "2023-10-16" @default.
• W2079733727 title "Structure and phase transitions in 0.5(Ba0.7Ca0.3TiO3)-0.5(BaZr0.2Ti0.8O3) from −100 °C to 150 °C" @default.
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• W2079733727 doi "https://doi.org/10.1063/1.4772741" @default.
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