Matches in SemOpenAlex for { <https://semopenalex.org/work/W2079737197> ?p ?o ?g. }
- W2079737197 abstract "Using thermal desorption and photoelectron spectroscopy to study the adsorption of pyridine on ZnO(1010), we find that the work function is significantly reduced from 4.5 eV for the bare ZnO surface to 1.6 eV for one monolayer of adsorbed pyridine. Further insight into the interface morphology and binding mechanism is obtained using density functional theory. Although semilocal density functional theory provides unsatisfactory total work functions, excellent agreement of the work function changes is achieved for all coverages. In a closed monolayer, pyridine is found to bind to every second surface Zn atom. The strong polarity of the Zn-pyridine bond and the molecular dipole moment act cooperatively, leading to the observed strong work function reduction. Based on simple alignment considerations, we illustrate that even larger work function modifications should be achievable using molecules with negative electron affinity. We expect the application of such molecules to significantly reduce the electron injection barriers at ZnO/organic heterostructures." @default.
- W2079737197 created "2016-06-24" @default.
- W2079737197 creator A5014876751 @default.
- W2079737197 creator A5028103689 @default.
- W2079737197 creator A5046665161 @default.
- W2079737197 creator A5046668694 @default.
- W2079737197 creator A5052538777 @default.
- W2079737197 creator A5067145443 @default.
- W2079737197 creator A5090540345 @default.
- W2079737197 date "2013-11-04" @default.
- W2079737197 modified "2023-10-09" @default.
- W2079737197 title "Large work function reduction by adsorption of a molecule with a negative electron affinity: Pyridine on ZnO$(10bar{1}0)$(101¯)" @default.
- W2079737197 cites W1491940380 @default.
- W2079737197 cites W1564743542 @default.
- W2079737197 cites W1615960000 @default.
- W2079737197 cites W1963612962 @default.
- W2079737197 cites W1965850324 @default.
- W2079737197 cites W1966810914 @default.
- W2079737197 cites W1967037771 @default.
- W2079737197 cites W1967181983 @default.
- W2079737197 cites W1968189595 @default.
- W2079737197 cites W1969523854 @default.
- W2079737197 cites W1976588344 @default.
- W2079737197 cites W1980904636 @default.
- W2079737197 cites W1981368803 @default.
- W2079737197 cites W1983134766 @default.
- W2079737197 cites W1983664947 @default.
- W2079737197 cites W1986167570 @default.
- W2079737197 cites W1986259051 @default.
- W2079737197 cites W1986564682 @default.
- W2079737197 cites W1986783124 @default.
- W2079737197 cites W1987489743 @default.
- W2079737197 cites W1987873499 @default.
- W2079737197 cites W1992422852 @default.
- W2079737197 cites W1994217721 @default.
- W2079737197 cites W1994880295 @default.
- W2079737197 cites W2001496420 @default.
- W2079737197 cites W2002300218 @default.
- W2079737197 cites W2003945084 @default.
- W2079737197 cites W2004043815 @default.
- W2079737197 cites W2004930595 @default.
- W2079737197 cites W2005432277 @default.
- W2079737197 cites W2006283251 @default.
- W2079737197 cites W2007767168 @default.
- W2079737197 cites W2008250107 @default.
- W2079737197 cites W2008856647 @default.
- W2079737197 cites W2010600969 @default.
- W2079737197 cites W2014310191 @default.
- W2079737197 cites W2014914608 @default.
- W2079737197 cites W2016154166 @default.
- W2079737197 cites W2017219559 @default.
- W2079737197 cites W2019017977 @default.
- W2079737197 cites W2022914117 @default.
- W2079737197 cites W2024296055 @default.
- W2079737197 cites W2024779862 @default.
- W2079737197 cites W2027424397 @default.
- W2079737197 cites W2027912768 @default.
- W2079737197 cites W2028250890 @default.
- W2079737197 cites W2029262974 @default.
- W2079737197 cites W2029862416 @default.
- W2079737197 cites W2030687437 @default.
- W2079737197 cites W2031462444 @default.
- W2079737197 cites W2034331582 @default.
- W2079737197 cites W2034740189 @default.
- W2079737197 cites W2034756256 @default.
- W2079737197 cites W2034971950 @default.
- W2079737197 cites W2037032522 @default.
- W2079737197 cites W2037952788 @default.
- W2079737197 cites W2040944715 @default.
- W2079737197 cites W2043201659 @default.
- W2079737197 cites W2043532201 @default.
- W2079737197 cites W2045655403 @default.
- W2079737197 cites W2048359305 @default.
- W2079737197 cites W2051559391 @default.
- W2079737197 cites W2052269441 @default.
- W2079737197 cites W2052637367 @default.
- W2079737197 cites W2055614283 @default.
- W2079737197 cites W2059885388 @default.
- W2079737197 cites W2060867370 @default.
- W2079737197 cites W2062099613 @default.
- W2079737197 cites W2062145281 @default.
- W2079737197 cites W2062820224 @default.
- W2079737197 cites W2062830106 @default.
- W2079737197 cites W2064452617 @default.
- W2079737197 cites W2065218629 @default.
- W2079737197 cites W2066101367 @default.
- W2079737197 cites W2067269954 @default.
- W2079737197 cites W2068190757 @default.
- W2079737197 cites W2068599464 @default.
- W2079737197 cites W2071800643 @default.
- W2079737197 cites W2072996664 @default.
- W2079737197 cites W2074066890 @default.
- W2079737197 cites W2075246038 @default.
- W2079737197 cites W2075839878 @default.
- W2079737197 cites W2076751112 @default.
- W2079737197 cites W2078205111 @default.
- W2079737197 cites W2083046786 @default.
- W2079737197 cites W2090715624 @default.
- W2079737197 cites W2091686724 @default.
- W2079737197 cites W2091708214 @default.