FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2079745663> ?p ?o ?g. }

• W2079745663 endingPage "10180" @default.
• W2079745663 startingPage "10174" @default.
• W2079745663 abstract "We have studied the effects of intermolecular and intramolecular coupling on the C-O stretching vibration of CO adsorbed on Platinum (111) by means of femtosecond broadband vibrational sum frequency generation (VSFG). Resonant intermolecular coupling is investigated through the coverage dependence of the VSFG signal. The experimental observations can be accurately modeled as lateral coupling of the molecular transition dipole moments; this coupling is invoked in the nonlinear optical response model as a local field correction. The linear polarizability, which appears in this model, is modified by both the dipole-dipole coupling and the population of bridged adsorption sites. By extending the formalism to include these effects, we deduce a vibrational polarizability of 0.32 A(3) from the data. Intramolecular coupling to the frustrated translational mode is observed as temperature dependence of the C-O stretch. The present data can be described either by pertubative or nonpertubative lineshape models from the literature. Measurements of the temperature dependence of the vibrational free induction decay indicate a population relaxation time T(1) of (0.8+/-0.1) ps, in agreement with the observed low-temperature linewidth. Moreover, the ability of this time-domain method to discriminate spectral inhomogeneity yields clear evidence of the order-disorder transition near 275 K. Above this temperature an inhomogeneous linewidth component of (12+/-3) cm(-1) is observed. This value allows us to estimate the structural heterogeneity of the disordered phase, which result agrees with published Monte Carlo simulations." @default.
• W2079745663 created "2016-06-24" @default.
• W2079745663 creator A5017647814 @default.
• W2079745663 creator A5030798677 @default.
• W2079745663 creator A5065822992 @default.
• W2079745663 date "2004-11-11" @default.
• W2079745663 modified "2023-09-23" @default.
• W2079745663 title "Frequency- and time-domain femtosecond vibrational sum frequency generation from CO adsorbed on Pt(111)" @default.
• W2079745663 cites W1963822816 @default.
• W2079745663 cites W1965372456 @default.
• W2079745663 cites W1966038757 @default.
• W2079745663 cites W1968607633 @default.
• W2079745663 cites W1969590348 @default.
• W2079745663 cites W1970057362 @default.
• W2079745663 cites W1971260270 @default.
• W2079745663 cites W1971374921 @default.
• W2079745663 cites W1973910947 @default.
• W2079745663 cites W1980117816 @default.
• W2079745663 cites W1981612683 @default.
• W2079745663 cites W1983479822 @default.
• W2079745663 cites W1988023846 @default.
• W2079745663 cites W1988521226 @default.
• W2079745663 cites W1989455951 @default.
• W2079745663 cites W1989510310 @default.
• W2079745663 cites W1992792017 @default.
• W2079745663 cites W1994542609 @default.
• W2079745663 cites W1997825945 @default.
• W2079745663 cites W2003540632 @default.
• W2079745663 cites W2009264564 @default.
• W2079745663 cites W2014539524 @default.
• W2079745663 cites W2020665965 @default.
• W2079745663 cites W2021065626 @default.
• W2079745663 cites W2029597432 @default.
• W2079745663 cites W2031510004 @default.
• W2079745663 cites W2033014123 @default.
• W2079745663 cites W2033080992 @default.
• W2079745663 cites W2033970021 @default.
• W2079745663 cites W2035586362 @default.
• W2079745663 cites W2036299712 @default.
• W2079745663 cites W2048232158 @default.
• W2079745663 cites W2049228054 @default.
• W2079745663 cites W2050273380 @default.
• W2079745663 cites W2055465627 @default.
• W2079745663 cites W2061561017 @default.
• W2079745663 cites W2065874815 @default.
• W2079745663 cites W2074081055 @default.
• W2079745663 cites W2074721785 @default.
• W2079745663 cites W2077221903 @default.
• W2079745663 cites W2083998869 @default.
• W2079745663 cites W2088312893 @default.
• W2079745663 cites W2090127748 @default.
• W2079745663 cites W2147986042 @default.
• W2079745663 doi "https://doi.org/10.1063/1.1802291" @default.
• W2079745663 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15549892" @default.
• W2079745663 hasPublicationYear "2004" @default.
• W2079745663 type Work @default.
• W2079745663 sameAs 2079745663 @default.
• W2079745663 citedByCount "30" @default.
• W2079745663 countsByYear W20797456632012 @default.
• W2079745663 countsByYear W20797456632013 @default.
• W2079745663 countsByYear W20797456632014 @default.
• W2079745663 countsByYear W20797456632015 @default.
• W2079745663 countsByYear W20797456632016 @default.
• W2079745663 countsByYear W20797456632018 @default.
• W2079745663 countsByYear W20797456632021 @default.
• W2079745663 crossrefType "journal-article" @default.
• W2079745663 hasAuthorship W2079745663A5017647814 @default.
• W2079745663 hasAuthorship W2079745663A5030798677 @default.
• W2079745663 hasAuthorship W2079745663A5065822992 @default.
• W2079745663 hasConcept C120665830 @default.
• W2079745663 hasConcept C121332964 @default.
• W2079745663 hasConcept C139287275 @default.
• W2079745663 hasConcept C142181693 @default.
• W2079745663 hasConcept C144024400 @default.
• W2079745663 hasConcept C149923435 @default.
• W2079745663 hasConcept C153642686 @default.
• W2079745663 hasConcept C166950319 @default.
• W2079745663 hasConcept C167735695 @default.
• W2079745663 hasConcept C173523689 @default.
• W2079745663 hasConcept C178790620 @default.
• W2079745663 hasConcept C184779094 @default.
• W2079745663 hasConcept C185592680 @default.
• W2079745663 hasConcept C24123453 @default.
• W2079745663 hasConcept C2908647359 @default.
• W2079745663 hasConcept C32909587 @default.
• W2079745663 hasConcept C41999313 @default.
• W2079745663 hasConcept C520434653 @default.
• W2079745663 hasConcept C71240020 @default.
• W2079745663 hasConcept C71515424 @default.
• W2079745663 hasConcept C75079739 @default.
• W2079745663 hasConceptScore W2079745663C120665830 @default.
• W2079745663 hasConceptScore W2079745663C121332964 @default.
• W2079745663 hasConceptScore W2079745663C139287275 @default.
• W2079745663 hasConceptScore W2079745663C142181693 @default.
• W2079745663 hasConceptScore W2079745663C144024400 @default.
• W2079745663 hasConceptScore W2079745663C149923435 @default.
• W2079745663 hasConceptScore W2079745663C153642686 @default.
• W2079745663 hasConceptScore W2079745663C166950319 @default.

• next