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- W2079748654 abstract "A new experimental method has been devised by which it is possible to study the deactivation of I*(5 2P1/2) by radical atoms as well as by stable molecular species. A small, steady-state concentration of I atoms is generated in a discharge–flow system, and then a fraction of these atoms is directly excited using the output from a pulsed iodine-atom, photochemical laser. The subsequent decay of I*(5 2P1/2) is observed by monitoring the I2(B→X) emission, the B[3Π(0+u)] state of I2 being formed by recombination, I*+ I + M → I2(B)+ M. The following quenching rate constants (cm3 molecule–1 s–1) at room temperature have been determined: kH2=(1.03 ± 0.06)× 10–13, kBr2=(5.5 ± 0.1)× 10–11, kCl2⩽ 5 × 10–14, kH=(4 ± 2)× 10–14, kI⩽ 5 × 10–13, kBr=(5.1 ± 1.9)× 10–13 and kCl=(2 ± 1)× 10–11." @default.
- W2079748654 created "2016-06-24" @default.
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- W2079748654 date "1985-01-01" @default.
- W2079748654 modified "2023-09-26" @default.
- W2079748654 title "Quenching of I*(2 P 1/2) by atomic and molecular hydrogen and halogens" @default.
- W2079748654 doi "https://doi.org/10.1039/f29858101695" @default.
- W2079748654 hasPublicationYear "1985" @default.
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