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• W2079755586 abstract "Abstract The stability of 1-methyl-1-propylpyrrolidinium bis(trifluoromethanesulfonyl)imide (PYR 13 TFSI) and 1-methyl-1-propylpyrrolidinium bis(fluorosulfonyl)imide (PYR 13 FSI) ionic liquids at elevated temperatures (60 °C) is investigated by ion chromatography. Additionally, the influence of the electrolyte salts, lithium hexafluorophosphate (LiPF 6 ), lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) and lithium perchlorate (LiClO 4 ), on the decomposition of both the ionic liquids was analysed over a long term stability study. It has been found out that TFSI has a much higher thermal stability than FSI. The addition of LiTFSI did not show any effect on the aging of both ionic liquid anions. However, PYR 13 FSI degraded when mixed with the electrolyte salts LiPF 6 and LiClO 4 , while PYR 13 TFSI did not. Finally, LiPF 6 forms the same hydrolysis products in the investigated ionic liquids as in the commonly used electrolytes based on organic solvents in lithium-ion batteries." @default.
• W2079755586 created "2016-06-24" @default.
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• W2079755586 date "2014-06-01" @default.
• W2079755586 modified "2023-09-23" @default.
• W2079755586 title "Thermal Aging of Anions in Ionic Liquids containing Lithium Salts by IC/ESI-MS" @default.
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• W2079755586 doi "https://doi.org/10.1016/j.electacta.2014.03.033" @default.
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