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- W2079757974 abstract "α-Tetraphosphor-trithio-dijodid 1 reagiert mit Metallcarbonylen M(CO)n (M = Ni, Fe) sowie mit gemischten Carbonyl-Verbindungen MLx(CO)y (M = Cr, Mo, W; L = THF, C7H8, CH3CN, C6H5CH3) unter Bildung von Komplexen des Types [M(α-P4S3J2)m(CO)n−m (M = 1–3). Mit (CO)3]2, während in Tetrahydrofuran unter Valenzdisproportionierung der ionogene Komplex [Co(α-P4S3J2)2(CO)3]⊕[Co(CO)4]⊖ gebildet wird. Verbrückte Komplexe [(CO)n−1M(α-P4S3J2)M(CO)n−1] konnten nicht erhalten werden. 1 fungiert demnach ausschließlich als 1-zähniger Ligand. Die dargestellten Komplexe besitzen daher trotz ihrer Schwerlöslichkeit eindeutig molekularen Aufbau und keine polymere Struktur. Contributions to the Chemistry of Phosphorus. 63. α-Tetraphosphorus-trithio-diiodide as a New Ligand in Carbonyl Complexes α-Tetraphosphor-trithio-dijodid 1 reacts with metal carbonyles M(CO)n (M = Ni, Fe) and with mixed carbonyl compounds MLx(CO)y (M = Cr, Mo, W; L = THF, C7H8, CH3CN, C6H5CH3) to give complexes of the type [M(α-P4S3J2)m(CO)n−m] (M = 1–3). With [Co(CO)4]2 in carbons disulfide or benzene results the substitution product [Co(α-P4S3J2)(CO)3]2, whereas in tetrahydrofurance the ionice complexe [Co(α-P4S3J2)2(CO)3]⊕[Co(CO)4]⊖ is for, ed via valence disproportionation. Bridged complexes [(CO)n−1M(α-P4S3J2)M(CO)n−1] could not be obtained. Therefore, 1 acts exclusively as monodentate ligand, and the prepared complexes possess unambiguouslya molecular and not a polymeric structure, in spite of their low solubility." @default.
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- W2079757974 title "Beitr�ge zur Chemie des Phosphors, 63. ?-Tetraphosphor-trithio-dijodid als neuer Ligand in Carbonyl-Komplexen" @default.
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