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• W2079758885 endingPage "054601" @default.
• W2079758885 startingPage "054601" @default.
• W2079758885 abstract "We prepared a series of high-quality single crystals of the filled skutterudite R Os 4 Sb 12 ( R = La, Ce, Pr, Nd, Sm) and performed precise X-ray structural analyses to investigate the relation between the crystal structure and rattling vibration of the guest R atoms. The results revealed that in a cage made of Sb, with increasing guest free space from La to Sm, the thermal displacement parameter of the R ion increases and the Einstein temperature, which represents the characteristic energy of the rattling, decreases. Anisotropic distribution of the electron density was observed, in particular for small R ions, which indicates that there is large anharmonicity along the [111] direction that reflects the specific shape of the Sb cage." @default.
• W2079758885 created "2016-06-24" @default.
• W2079758885 creator A5045133781 @default.
• W2079758885 creator A5045302692 @default.
• W2079758885 date "2011-05-15" @default.
• W2079758885 modified "2023-10-17" @default.
• W2079758885 title "Rattling Vibrations Observed by Means of Single-Crystal X-ray Diffraction in the Filled Skutterudite <i>R</i>Os₄Sb₁₂ (<i>R</i> = La, Ce, Pr, Nd, Sm)" @default.
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• W2079758885 doi "https://doi.org/10.1143/jpsj.80.054601" @default.
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