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- W2079761241 abstract "Al(OTf)3 generates blue carbocations from retinyl acetate. The mechanism appears to be exclusively water-derived induced Brønsted acidity causing loss of acetic acid, not Lewis-mediated acetate abstraction. Dry DCM (1 ppm water) avoided water interference. The hindered base 2,6-di-tert-butylpyridine, used to distinguish between Lewis- and Brønsted acidity, was also probed. The results implicate a possible mechanism for similar transformations involving carbocations." @default.
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- W2079761241 date "2010-02-01" @default.
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- W2079761241 title "Metal triflates: On the question of Lewis versus Brønsted acidity in retinyl carbocation formation" @default.
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- W2079761241 doi "https://doi.org/10.1016/j.molcata.2009.10.023" @default.
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