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- W2079764602 abstract "The ligand series 2-[1-(2,4-dibenzhydryl-6-methylphenylimino)ethyl]-6-[1-(arylimino)ethyl]pyridines and the iron(II) chloride complexes thereof have been synthesized and characterized by elemental and spectroscopic analyses. The molecular structures of C1 and C2, determined by single-crystal X-ray diffraction analysis, confirmed a pseudo-square-pyramidal geometry at the iron center. Upon treatment with either MAO or MMAO, all iron pre-catalysts possessed good thermo-stability and exhibited high activities [up to 5.22 × 107 g mol−1(Fe) h−1] toward ethylene polymerization, producing highly linear polyethylene products. Optimization of the reaction parameters gave polyethylenes with narrow molecular weight distributions, indicating that single-site active species were formed; the molecular weights of the resultant polyethylenes could also be controlled." @default.
- W2079764602 created "2016-06-24" @default.
- W2079764602 creator A5033474482 @default.
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- W2079764602 date "2012-01-01" @default.
- W2079764602 modified "2023-10-18" @default.
- W2079764602 title "Controlling the ethylene polymerization parameters in iron pre-catalysts of the type 2-[1-(2,4-dibenzhydryl-6-methylphenylimino)ethyl]-6-[1-(arylimino)ethyl] pyridyliron dichloride" @default.
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- W2079764602 doi "https://doi.org/10.1016/j.polymer.2011.11.024" @default.
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