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- W2079766660 abstract "A molecularly imprinted nanocapsule was prepared, which showed excellent site accessibility and potential in delivery applications. The monomer−template complex (Est−Vinyl) was synthesized by the reaction of 3-isopropenyl-α,α-dimethylbenzyl isocyanate with estrone, where the template was linked to a polymerizable vinyl group via a thermally reversible urethane bond. Microemulsion polymerization of Est−Vinyl, styrene, and divinylbenzene was carried out in water and octanol by using potassium persulfate as an initiator to produce a nanocapsule having a cross-linked polymeric wall. The hollow structure of the nanocapsule was confirmed by transmission electron microscopy. The template was removed from the polymeric wall by means of a simple thermal reaction. In aqueous media, the imprinted nanocapsule solubilized hydrophobic pyrene. When the imprinted nanocapsules were previously incubated in a template (estrone) solution, pyrene could not transfer effectively into the interior of the nanocapsules, suggesting that the imprinted sites were blocked by the template molecules." @default.
- W2079766660 created "2016-06-24" @default.
- W2079766660 creator A5009662056 @default.
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- W2079766660 date "2006-03-31" @default.
- W2079766660 modified "2023-10-17" @default.
- W2079766660 title "Preparation of a Molecularly Imprinted Polymeric Nanocapsule with Potential Use in Delivery Applications" @default.
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- W2079766660 doi "https://doi.org/10.1021/ma052480q" @default.
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