Matches in SemOpenAlex for { <https://semopenalex.org/work/W2079767557> ?p ?o ?g. }
- W2079767557 endingPage "192" @default.
- W2079767557 startingPage "177" @default.
- W2079767557 abstract "Organic ions are withdrawn directly from the condensed phase in molecular secondary ion mass spectrometry (SIMS). In common with other desorption ionization methods, SIMS provides both molecular weight and structural information about complex molecules; other characteristics include a persistence of ion emission, a propensity for cluster ion formation, and a sensitivity to matrix effects. Tandem mass spectrometry (MS/MS) can be advantageously coupled with SIMS to establish ionic relationships in the gas phase, to deduce ion structure, and in analytical studies. In this work, capabilities for isomer differentiation are demonstrated in the natural products field, the value of solid matrices in desorption ionization is illustrated, and in situ isotopic selection is used to interpret spectra. Various types of cluster ions generated in SIMS are analyzed by MS/MS, which allows a distinction between weakly and strongly bound complexes. The cluster ions formed between the cation of thiamine and glycerol shows a strong sample/solvent interaction and consequently glycerol is too reactive a solvent to be used in obtaining the mass spectrum of thiamine. Gas phase fragmentations of the intact cation of carnitine are strikingly different from those observed in the SIMS spectrum, in contrast to the behavior of thiamine, cocaine and candicine for which collision-induced dissociations provide a good guide to desorption ionization mass spectra." @default.
- W2079767557 created "2016-06-24" @default.
- W2079767557 creator A5036827887 @default.
- W2079767557 creator A5037113533 @default.
- W2079767557 creator A5040044165 @default.
- W2079767557 creator A5071668469 @default.
- W2079767557 date "1984-02-01" @default.
- W2079767557 modified "2023-09-28" @default.
- W2079767557 title "MS/MS spectra of organic ions generated by secondary ion mass spectrometry" @default.
- W2079767557 cites W1595752073 @default.
- W2079767557 cites W1964873076 @default.
- W2079767557 cites W1978281742 @default.
- W2079767557 cites W1983075250 @default.
- W2079767557 cites W1989956937 @default.
- W2079767557 cites W2004925380 @default.
- W2079767557 cites W2014121774 @default.
- W2079767557 cites W2017182386 @default.
- W2079767557 cites W2018242809 @default.
- W2079767557 cites W2018924424 @default.
- W2079767557 cites W2019326214 @default.
- W2079767557 cites W2021193632 @default.
- W2079767557 cites W2025376419 @default.
- W2079767557 cites W2029679575 @default.
- W2079767557 cites W2030373106 @default.
- W2079767557 cites W2031478014 @default.
- W2079767557 cites W2045237334 @default.
- W2079767557 cites W2045977493 @default.
- W2079767557 cites W2046041881 @default.
- W2079767557 cites W2052326125 @default.
- W2079767557 cites W2053199917 @default.
- W2079767557 cites W2078409407 @default.
- W2079767557 cites W2085851162 @default.
- W2079767557 cites W2111285639 @default.
- W2079767557 cites W2113461977 @default.
- W2079767557 cites W2136708725 @default.
- W2079767557 cites W2170423576 @default.
- W2079767557 cites W2316012615 @default.
- W2079767557 cites W2949999845 @default.
- W2079767557 cites W2951702734 @default.
- W2079767557 cites W4241885449 @default.
- W2079767557 cites W4242499287 @default.
- W2079767557 cites W4295009278 @default.
- W2079767557 doi "https://doi.org/10.1016/0168-1176(84)85042-9" @default.
- W2079767557 hasPublicationYear "1984" @default.
- W2079767557 type Work @default.
- W2079767557 sameAs 2079767557 @default.
- W2079767557 citedByCount "24" @default.
- W2079767557 crossrefType "journal-article" @default.
- W2079767557 hasAuthorship W2079767557A5036827887 @default.
- W2079767557 hasAuthorship W2079767557A5037113533 @default.
- W2079767557 hasAuthorship W2079767557A5040044165 @default.
- W2079767557 hasAuthorship W2079767557A5071668469 @default.
- W2079767557 hasConcept C11174340 @default.
- W2079767557 hasConcept C113196181 @default.
- W2079767557 hasConcept C145148216 @default.
- W2079767557 hasConcept C147789679 @default.
- W2079767557 hasConcept C150394285 @default.
- W2079767557 hasConcept C162356407 @default.
- W2079767557 hasConcept C162711632 @default.
- W2079767557 hasConcept C16291436 @default.
- W2079767557 hasConcept C178790620 @default.
- W2079767557 hasConcept C185592680 @default.
- W2079767557 hasConcept C187529661 @default.
- W2079767557 hasConcept C198291218 @default.
- W2079767557 hasConcept C31827203 @default.
- W2079767557 hasConcept C38438003 @default.
- W2079767557 hasConcept C40325409 @default.
- W2079767557 hasConcept C43617362 @default.
- W2079767557 hasConcept C66594872 @default.
- W2079767557 hasConcept C77671233 @default.
- W2079767557 hasConceptScore W2079767557C11174340 @default.
- W2079767557 hasConceptScore W2079767557C113196181 @default.
- W2079767557 hasConceptScore W2079767557C145148216 @default.
- W2079767557 hasConceptScore W2079767557C147789679 @default.
- W2079767557 hasConceptScore W2079767557C150394285 @default.
- W2079767557 hasConceptScore W2079767557C162356407 @default.
- W2079767557 hasConceptScore W2079767557C162711632 @default.
- W2079767557 hasConceptScore W2079767557C16291436 @default.
- W2079767557 hasConceptScore W2079767557C178790620 @default.
- W2079767557 hasConceptScore W2079767557C185592680 @default.
- W2079767557 hasConceptScore W2079767557C187529661 @default.
- W2079767557 hasConceptScore W2079767557C198291218 @default.
- W2079767557 hasConceptScore W2079767557C31827203 @default.
- W2079767557 hasConceptScore W2079767557C38438003 @default.
- W2079767557 hasConceptScore W2079767557C40325409 @default.
- W2079767557 hasConceptScore W2079767557C43617362 @default.
- W2079767557 hasConceptScore W2079767557C66594872 @default.
- W2079767557 hasConceptScore W2079767557C77671233 @default.
- W2079767557 hasIssue "2" @default.
- W2079767557 hasLocation W20797675571 @default.
- W2079767557 hasOpenAccess W2079767557 @default.
- W2079767557 hasPrimaryLocation W20797675571 @default.
- W2079767557 hasRelatedWork W1972145719 @default.
- W2079767557 hasRelatedWork W2005829364 @default.
- W2079767557 hasRelatedWork W2021877237 @default.
- W2079767557 hasRelatedWork W2025085133 @default.
- W2079767557 hasRelatedWork W2047986932 @default.
- W2079767557 hasRelatedWork W2068204494 @default.