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- W2079770180 abstract "Abstract Composite nickel/thallium hexacyanoferrates were prepared as thin films on electrode surfaces. Electrodeposition of composite films was achieved by potential cycling in the solution for modification containing, in addition to potassium salt electrolyte, nickel(II), thallium(I), and hexacyanoferrate(III). Depending on the relative amounts of thallium to nickel, either a mixed phase with respect to interstitial ions was formed in which Tl(I) cations substitute potassium countercations at interstitial positions of nickel hexacyanoferrate or mixed phases of hexacyanoferrates of nickel and thallium were produced. Due to large differences in ionic radii of Ni(II) and Tl(I), formation of heteronuclear nickel/thallium hexacyanoferrate, in which both nickel(II) and thallium(I) are nitrogen-coordinated within the cyanometallate lattice, was rather unlikely. On basis of the stripping-like determinations, we propose a stoichiometric formula, K 2− z Tl I z Ni II [Fe II (CN)] 6 ( z ≤1), for the system in which interstitial K + was substituted with Tl(I); and a more general K x Tl I z Ni II y [Fe II (CN)] 6 formula that also reflects the possibility of codeposition of separate nickel hexacyanoferrate and thallium hexacyanoferrate microstructures during the film growth. Mixed nickel/thallium hexacyanoferrate films showed good stability during voltammetric potential cycling. In addition to potassium salt electrolytes, well-defined and reversible cyclic voltammetric responses were also obtained in sodium and cesium electrolytes." @default.
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- W2079770180 date "2001-08-01" @default.
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- W2079770180 title "Films of mixed nickel(II) and thallium(I) hexacyanoferrates(III,II): voltammetric preparation and characterization" @default.
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- W2079770180 doi "https://doi.org/10.1016/s0013-4686(01)00718-6" @default.
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