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- W2079773362 abstract "Abstract Two new Cd(II) complexes with a 3-(2-pyridyl)pyrazole-based ligand, [Cd(L)2(SCN)2] (1) and {[Cd(L)2N3](ClO4)}n (2) (L=3-(2-pyridyl)pyrazol-1-ylmethylbenzene) were synthesized and structurally characterized by elemental analyses, IR and single crystal X-ray diffraction analysis. Complex 1 crystallizes in the monoclinic system, space group C2/c, with a=14.833(3), b=13.790(3), c=15.970(3) A, β=110.89(3)° and Z=4, while 2 crystallizes in the monoclinic system, space group P21/c, with a=13.622(4), b=23.286(7), c=10.547(3) A, β=111.084(6)° and Z=4. In the two complexes, the Cd(II) centers are coordinated by six nitrogen atoms, in which four from two distinct L ligands and two from thiocyanato (1) or azido (2) anions. Complex 1 has a mononuclear structure, whereas 2 has a 1D chain structure bridged by azido anions. In 2, the azido adopts a μ-1,3-trans coordination mode, which is not common in the azide Cd(II) complexes. In addition, in the structure of 2, the 1D chains were further assembled into a quasi-3D supramolecular network by the C–H⋯O hydrogen-bonding interactions. The structural difference of the two complexes is attributable to the different anions, which have different coordination natures." @default.
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- W2079773362 date "2005-11-01" @default.
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- W2079773362 title "Synthesis and crystal structures of two new Cd(II) complexes with 3-(2-pyridy)pyrazole-based ligand: influence of anions" @default.
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- W2079773362 doi "https://doi.org/10.1016/j.molstruc.2005.07.001" @default.
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