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- W2079774619 abstract "We report an experimental investigation of the reaction O(3P)+HCl(v=2,J)→OH(v′=0 and 1,N′)+Cl(2P), where HCl is prepared in a single rovibronic level using a tunable optical parametric oscillator and the rovibronic levels of the OH reaction product are monitored using laser-induced fluorescence. The nascent rotational state distributions in OH(v′=0 and 1) have been measured as a function of the initial rotational state J of HCl(v=2). These distributions are substantially rotationally excited and exhibit a shift towards higher N′ as J is increased. Comparable branching into OH(v′=0) and OH(v′=1) is observed. The reaction cross section is found to increase markedly with reagent rotation: the increase is approximately a factor of 3 over the range J=1–10 of HCl(v=2), but is not necessarily monotonic for low J." @default.
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- W2079774619 date "1987-12-15" @default.
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- W2079774619 title "Rovibronic state to rovibronic state reaction dynamics: O(<sup>3</sup><i>P</i>)+HCl(<i>v</i>=2,<i>J</i>)→OH(<i>v</i>′,<i>N</i>′)+Cl(<sup>2</sup><i>P</i>)" @default.
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- W2079774619 doi "https://doi.org/10.1063/1.453328" @default.
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