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- W2079774858 abstract "The Diels–Alder reaction of ethyl (−)-(Z)-(R)S-2-methyl-3-(p-tolylsulfinyl)propenoate (6) with cyclopentadiene gave the cycloadducts 7, 8, and 9 in a high diastereoselective manner. The cycloadduct 7 was transformed into the acetal (−)-25. The racemic 25 was used as an intermediate in the synthesis of (±)-β-santalol. Thus, the chiral acetal (−)-25 should provide a route to (−)-β-santalol. The cycloadduct 8 was converted into (+)-epi-β-santalene in 11 steps." @default.
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- W2079774858 date "1988-02-01" @default.
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- W2079774858 title "The Asymmetric Diels–Alder Cycloaddition Using Ethyl (−)-(<i>Z</i>)-(<i>R</i>)<sub>S</sub>-2-Methyl-3-(<i>p</i>-tolylsulfinyl)propenoate: Application to an Enantioselective Synthesis of (+)-<i>epi</i>-β-Santalene" @default.
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