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- W2079779644 abstract "Abstract Two new silicate hydrates, (C20H30N2)8 · [Si8O20]2 · 110H2O (1) and (C20H30N2)4 · [Si8O20] · 42H2O (2) have been prepared and their structures determined using single-crystal X-ray diffraction. The structures of 1 and 2 are formed from silicate octameric cubes bridged by hydrogen-bonded water molecules. Crystal data for 1: P-1, Z=1, a=18.508(1) A, b=20.393(1) A, c=20.784(1) A, α=97.747(4)°, β=92.249(5)°, γ=116.396(3)°; 2: P-1, Z=1, a=14.345(1) A, b=14.855(1) A, c=16.162(1) A, α=80.339(5)°, β=84.916(5)°, γ=67.805(5)°. Both 1 and 2 have apertures formed by hydrogen-bonded water molecules which are approximately 9.5×5.5 and 12.0×9.0 A in 1 and 2, respectively. The structures of both hydrates have numerous weak C–H ⋯ O hydrogen bonds between the organic cations and water molecules. The importance of these and organic–inorganic electrostatic forces are discussed in the context of zeolite synthesis." @default.
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- W2079779644 date "2001-03-01" @default.
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- W2079779644 title "Two new silicate hydrates (C20H30N2)8·[Si8O20]2·110H2O and (C20H30N2)4·[Si8O20]·42H2O, and their implications for the role of non-covalent interactions in high-silica zeolite synthesis" @default.
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- W2079779644 doi "https://doi.org/10.1016/s1387-1811(00)00356-5" @default.
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