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- W2079781377 abstract "The reaction of [Au2(μ-CH2PPh2CH2)2(tht)2](CIO4)2 or [Au2(μ-CH2PPh2CH2)2(PPh3)(tht)](CIO4)2 (tht=tetrahydrothiophene) with various dithiocarbamates gives the cationic or neutral complexes [Au2(μ-CH2PPh2CH2)2{S(MeS)CNHR}2](CIO4)2, [Au2(μ- CH2PPh2CH2)2(PPh3){S(Mes)CNHR}](CIO4)2 or [Au2(μ-CH2PPh2CH2)2(S2CNR2)2]. Displacement of tht from [Au2(μ-CH2PPh2CH2)2(R′)(tht)](CIO4) (R′=C6F5 or 2,4,6-C6F3H2) gives new cationic tetranuclear complexes [{Au2(μ-CH2PPh2CH2)2(R′)}2(μ- S2CNR2)](CIO4) in which the dithiocarbamate acts as a bridging ligand. The structure of [Au2(μ-CH2PPh2- CH2)2(S2CNMe2)2] has been established by an X-ray diffraction study and shows that the dithiocarbamate is unidentate." @default.
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- W2079781377 date "1994-08-01" @default.
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- W2079781377 title "Di- and tetranuclear gold(II) complexes with dithiocarbamate and related ligands. X-ray structure of Au2(μ-CH2PPh2CH2)2(S2CNMe2)2]" @default.
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- W2079781377 doi "https://doi.org/10.1016/0020-1693(94)03990-9" @default.
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