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- W2079785083 abstract "Abstract Throughout the world, the drilling process generates a huge variety of contaminated solid waste. The environmental impact of these side products depends on their composition and concentration but also on the employed drilling technologies, based on water base mud (WBM) or oil base mud (OBM). The various local and international Guidelines will gradually ban the discharge into the sea of these contaminated drilling waste. The OSPAR 2000/3 decisions will soon prohibit their disposal into the sea and will recommend a zero % discharge of organic based drilling fluids. With the emphasis placed on environmental safety, the oil companies are developing economical methodologies to clean oil contaminated field waste, such as cuttings or used drilling muds. One of the major challenge is to develop sensitive analytical tool to measure in a short time low oil content in a great variety of mineral matrix without major interference. In this framework, this paper provides answers concerning the problem of quantification of low oil content in complex solid waste. A study has been performed to demonstrate the ability of the Pollut-Eval method to characterize and quantify hydrocarbon contamination without any pretreatment. In a first step, analytical results of pure hydrocarbon cuts commonly used in drilling muds (iso and n-paraffin, α olefin, ester and diesel cuts) will be presented to demonstrate the qualitative and quantitative efficiency of the method. In a second step, evaluation of the total organic content of various drilling muds will be compared to their hydrocarbon concentration to demonstrate that no major interference occurred in the characterization or quantification of these petroleum cuts despite the various and complex mud formulations. In a last step, Pollut-Eval residual oil content (ROC) and total organic carbon (TOC) of undersea discharged cuttings sampled at 200 m depth (more or less distant from an offshore rig) will be presented and compared to capillary gas phase chromatography results. As a conclusion, Pollut-eval performance will be discussed and compared to other methods commonly used in oil industry: global carbon organic determination by catalytic oxidation and retort kit distillation." @default.
- W2079785083 created "2016-06-24" @default.
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- W2079785083 date "2002-09-29" @default.
- W2079785083 modified "2023-09-25" @default.
- W2079785083 title "Pollut-Eval: An Innovative Tool for Direct Hydrocarbon Characterization in Oil Base Mud & Cuttings" @default.
- W2079785083 cites W2008881522 @default.
- W2079785083 doi "https://doi.org/10.2118/77472-ms" @default.
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