FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2079789722> ?p ?o ?g. }

• W2079789722 endingPage "75" @default.
• W2079789722 startingPage "75" @default.
• W2079789722 abstract "A study of deoxyadenosine crystals (anhydrous form) after irradiation at 10 K found four base-centered radicals and one sugar-centered radical. Radical R1, thermally stable to about 100 K and photobleachable easily with white light, was the product of deprotonation at the amino group by the primary radical cation. Radical R2, also thermally stable to about 100 K, was the product of protonation at N3 of the primary radical anion. Radical R3, stable to about 170 K, was centered in the deoxyribose moiety and evidently was the result of net hydrogen abstraction from C4'. Radicals R4 and R5 were the C2 and C8 H-addition products with couplings typical of those species. Both R4 and R5 were formed at 10 K and were stable at room temperature. The behavior of R1 in several systems provides additional evidence for significant involvement of the hydrogen-bonding environment in controlling the stabilization (or formation) of radicals resulting directly from ionization, as described previously (Radiat. Res. 131, 272-284, 1992). From comparison of amino-group hydrogen-bonding environments in which radicals with the structure of R1 were stabilized, we conclude that oxygen atoms as proton acceptors are important in permitting the charge and spin separation necessary for radical stabilization. In particular, oxygens of ROH structures seem most efficient by readily permitting a multi-proton shuffle through a mechanism amounting to proton exchange. The collective results show that stabilization of these products is unlikely unless the charge and spin can be separated by at least one intervening molecule." @default.
• W2079789722 created "2016-06-24" @default.
• W2079789722 creator A5013474663 @default.
• W2079789722 creator A5018904375 @default.
• W2079789722 creator A5033161682 @default.
• W2079789722 creator A5085836102 @default.
• W2079789722 date "1998-01-01" @default.
• W2079789722 modified "2023-10-13" @default.
• W2079789722 title "Electron Spin Resonance and Electron Nuclear Double Resonance Study of X-Irradiated Deoxyadenosine: Proton Transfer Behavior of Primary Ionic Radicals" @default.
• W2079789722 cites W1520315220 @default.
• W2079789722 cites W1968644257 @default.
• W2079789722 cites W1969926994 @default.
• W2079789722 cites W1981912201 @default.
• W2079789722 cites W1996877293 @default.
• W2079789722 cites W2002595880 @default.
• W2079789722 cites W2016344675 @default.
• W2079789722 cites W2020623241 @default.
• W2079789722 cites W2026156690 @default.
• W2079789722 cites W2032173016 @default.
• W2079789722 cites W2036840552 @default.
• W2079789722 cites W2063105668 @default.
• W2079789722 cites W2070407799 @default.
• W2079789722 cites W2076443199 @default.
• W2079789722 cites W2084092092 @default.
• W2079789722 cites W2087353123 @default.
• W2079789722 cites W2091349715 @default.
• W2079789722 cites W2124655503 @default.
• W2079789722 cites W2234317061 @default.
• W2079789722 cites W2313987314 @default.
• W2079789722 cites W2324593760 @default.
• W2079789722 cites W2326740494 @default.
• W2079789722 cites W2334458135 @default.
• W2079789722 cites W2411833453 @default.
• W2079789722 cites W2413657152 @default.
• W2079789722 cites W2415724729 @default.
• W2079789722 cites W2951602852 @default.
• W2079789722 cites W2951983122 @default.
• W2079789722 doi "https://doi.org/10.2307/3579684" @default.
• W2079789722 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/9421157" @default.
• W2079789722 hasPublicationYear "1998" @default.
• W2079789722 type Work @default.
• W2079789722 sameAs 2079789722 @default.
• W2079789722 citedByCount "45" @default.
• W2079789722 countsByYear W20797897222012 @default.
• W2079789722 countsByYear W20797897222014 @default.
• W2079789722 countsByYear W20797897222015 @default.
• W2079789722 countsByYear W20797897222019 @default.
• W2079789722 countsByYear W20797897222020 @default.
• W2079789722 crossrefType "journal-article" @default.
• W2079789722 hasAuthorship W2079789722A5013474663 @default.
• W2079789722 hasAuthorship W2079789722A5018904375 @default.
• W2079789722 hasAuthorship W2079789722A5033161682 @default.
• W2079789722 hasAuthorship W2079789722A5085836102 @default.
• W2079789722 hasConcept C112887158 @default.
• W2079789722 hasConcept C118629725 @default.
• W2079789722 hasConcept C121332964 @default.
• W2079789722 hasConcept C139066938 @default.
• W2079789722 hasConcept C145148216 @default.
• W2079789722 hasConcept C161790260 @default.
• W2079789722 hasConcept C17365422 @default.
• W2079789722 hasConcept C178790620 @default.
• W2079789722 hasConcept C181199279 @default.
• W2079789722 hasConcept C185592680 @default.
• W2079789722 hasConcept C187961010 @default.
• W2079789722 hasConcept C2777709666 @default.
• W2079789722 hasConcept C2780636463 @default.
• W2079789722 hasConcept C29773484 @default.
• W2079789722 hasConcept C30095370 @default.
• W2079789722 hasConcept C32909587 @default.
• W2079789722 hasConcept C46141821 @default.
• W2079789722 hasConcept C54516573 @default.
• W2079789722 hasConcept C552990157 @default.
• W2079789722 hasConcept C55493867 @default.
• W2079789722 hasConcept C62520636 @default.
• W2079789722 hasConcept C66887884 @default.
• W2079789722 hasConcept C75473681 @default.
• W2079789722 hasConcept C81022585 @default.
• W2079789722 hasConcept C96444392 @default.
• W2079789722 hasConceptScore W2079789722C112887158 @default.
• W2079789722 hasConceptScore W2079789722C118629725 @default.
• W2079789722 hasConceptScore W2079789722C121332964 @default.
• W2079789722 hasConceptScore W2079789722C139066938 @default.
• W2079789722 hasConceptScore W2079789722C145148216 @default.
• W2079789722 hasConceptScore W2079789722C161790260 @default.
• W2079789722 hasConceptScore W2079789722C17365422 @default.
• W2079789722 hasConceptScore W2079789722C178790620 @default.
• W2079789722 hasConceptScore W2079789722C181199279 @default.
• W2079789722 hasConceptScore W2079789722C185592680 @default.
• W2079789722 hasConceptScore W2079789722C187961010 @default.
• W2079789722 hasConceptScore W2079789722C2777709666 @default.
• W2079789722 hasConceptScore W2079789722C2780636463 @default.
• W2079789722 hasConceptScore W2079789722C29773484 @default.
• W2079789722 hasConceptScore W2079789722C30095370 @default.
• W2079789722 hasConceptScore W2079789722C32909587 @default.
• W2079789722 hasConceptScore W2079789722C46141821 @default.
• W2079789722 hasConceptScore W2079789722C54516573 @default.
• W2079789722 hasConceptScore W2079789722C552990157 @default.
• W2079789722 hasConceptScore W2079789722C55493867 @default.

• next