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- W2079792220 abstract "The Doong−Yang model, which is used for predicting gas mixture adsorption equilibrium from pure-component isotherms of the Dubinin type, is modified by incorporating the Lewis relationship. The modified model is tested against experimental data for four binary systems, including a like-component (or nearly ideal) mixture, CH4 + C2H6, a moderately nonideal mixture, CO2 + C2H4, and two highly nonideal mixtures, CO2 + C3H8 and CO2 + H2O. Comparisons are made with the ideal adsorbed solution (IAS) theory and the Bering model. Results show that the proposed model is the best for the like-component mixture and the moderately nonideal mixture. In contrast, for the highly nonideal mixtures, the original Doong−Yang model is the only one among the four models that can predict CO2 + C3H8 adsorption correctly. The IAS theory and the Bering model have similar predictions and are suitable only for like-component mixtures. The new model requires a simple numerical iteration but is easy to use; no new parameters are required. Theoretical reasons are given for the fact that the original Doong−Yang model is best for nonideal mixtures, whereas the modified Doong−Yang model is best for ideal mixtures." @default.
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- W2079792220 date "2005-08-01" @default.
- W2079792220 modified "2023-09-26" @default.
- W2079792220 title "A Modification of the Doong−Yang Model for Gas Mixture Adsorption Using the Lewis Relationship" @default.
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- W2079792220 doi "https://doi.org/10.1021/la051210y" @default.
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