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• W2079794100 abstract "The reduction of CO2 has been examined at gold and platinum microelectrodes in solutions of 0.1 M tetraethylammonium perchlorate (TEAP) in dimethyl sulfoxide (DMSO), acetonitrile (MeCN) and mixed solvent systems. The gold microelectrode in 90 % MeCN/10 % DMSO produced currents 4 times larger than in pure DMSO while still showing a large potential window over which reduction currents can be measured. Films of polyaniline were insoluble in MeCN and acted as a diffusional barrier for CO2 reduction. Polyaniline was soluble in DMSO solutions, but the adsorbates which remained following polyaniline dissolution helped to lower the CO2 reduction overpotential, producing a broad current plateau of 500 mV for the measurement of CO2 concentrations." @default.
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• W2079794100 date "2000-02-01" @default.
• W2079794100 modified "2023-09-26" @default.
• W2079794100 title "CO2 Gas Sensing at Microelectrodes in Nonaqueous Solvents" @default.
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• W2079794100 doi "https://doi.org/10.1002/(sici)1521-4109(200002)12:2<105::aid-elan105>3.0.co;2-2" @default.
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