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• W2079806822 startingPage "2093" @default.
• W2079806822 abstract "2H-azirine, a less known acetonitrile isomer, is observed in matrix IR spectra from the precursor exposed to radiation from laser ablation of transition-metals. Its vibrational characteristics confirm the previous results, and those for the deuterated and <TEX>$^{13}C$</TEX> substituted isotopomers are also newly reported. The weak absorptions are traced to the low production yield due to its high energy and low extinction constants. IRC computations reveal smooth inter-conversion between 2H-azirine and <TEX>$CH_2NCH$</TEX>, providing a rationale for the observed variation of their relative contents during photolysis." @default.
• W2079806822 created "2016-06-24" @default.
• W2079806822 creator A5036641250 @default.
• W2079806822 date "2014-07-20" @default.
• W2079806822 modified "2023-09-23" @default.
• W2079806822 title "Matrix Infrared Spectra and DFT Computations of 2H-Azirine Produced from Acetonitrile by Laser-Ablation Plume Radiation" @default.
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• W2079806822 doi "https://doi.org/10.5012/bkcs.2014.35.7.2093" @default.
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