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- W2079832747 abstract "Metallic nanoparticles of rhodium were prepared by using the newly synthesized N,N-bis-succinamide-based dendrimer as stabilizers. The Rh nanoparticles were spherical shaped with a particle size of ∼2 nm. The dendrimer Rh-encapsulated nanoparticles (Rh-DENs) were immobilized on glassy carbon electrode (GCE) and their electrocatalytic activity towards hydrogen peroxide reduction was investigated using cyclic voltammetry and chronoamperometry. The Rh-DENs modified GCE showed excellent electrocatalytic activity for hydrogen peroxide reduction reactions. The steady-state cathodic current response of the modified electrode at −0.3 V (vs SCE) in phosphate buffer (pH 7.0) showed a linear response to hydrogen peroxide concentration ranging from 8 to 30 μM with a detection limit and sensitivity of 5 μM and 0.03103 × 10−6 A μM−1, respectively." @default.
- W2079832747 created "2016-06-24" @default.
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- W2079832747 date "2009-01-01" @default.
- W2079832747 modified "2023-10-16" @default.
- W2079832747 title "Dendrimer-rhodium nanoparticle modified glassy carbon electrode for amperometric detection of hydrogen peroxide" @default.
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- W2079832747 doi "https://doi.org/10.1016/j.aca.2008.10.062" @default.
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