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- W2079834476 abstract "The first example of the formation of a sulfone concomitant with double bond migration during photooxidation of a sulfide is reported. Evidence is presented which demonstrates that the double bond migration is not a result of a prior acid-catalyzed rearrangement of an unrearranged sulfone precursor. This unusual observation is used to argue that the sulfone is formed via rearrangement of a hydroperoxy sulfonium ylide intermediate." @default.
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- W2079834476 date "2002-01-16" @default.
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- W2079834476 title "The First Example of a Singlet Oxygen Induced Double Bond Migration during Sulfide Photooxidation. Experimental Evidence for Sulfone Formation via a Hydroperoxy Sulfonium Ylide" @default.
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- W2079834476 doi "https://doi.org/10.1021/jo016219t" @default.
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