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- W2079841799 abstract "Abstract The formation of negative ions by attachment of low energy electrons to CF3CN and CF3NC was studied. The kinetic energy release of the fragments formed was analysed. In both isomers, dissociative attachment leading to CN− and CF3· is the dominant channel. An evaluation of the energetics of these reactions leads directly to the bond dissociation energies D(F3CCN) ≤ 4.4 ± 0.2 eV, D(F3CNC) ≤ 3.9 ± 0.2 eV, and the heats of formation ΔHf298 (CF3CN) ≥ −4.8 ± 0.3 eV and ΔHf298 (CF3NC) ≥ −4.3 ± 0.3 eV. The well-known anions CN−, F−, and CF3−, are observed from both compounds. In addition, electron attachment only to CF3NC yields a variety of other negative ions (CF−, C2N−, F2−·, CF3N−·, CF2N−, CFN−·)." @default.
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- W2079841799 date "1986-09-01" @default.
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- W2079841799 title "The isomers CF3NC and CF3CN. Formation and dissociation of the anions formed on electron attachment" @default.
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- W2079841799 doi "https://doi.org/10.1016/0168-1176(86)85056-x" @default.
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