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- W2079854032 abstract "Abstract The appearance energy of the α-C protonated 6-oxafulvalene, C5H5CO+, generated from the fragmentation of ionized (CO)3MnC5H4CHO (estimated ΔHf0 of neutral complex −602 ± 5 kJ mol−1) gave a value of 705 ± 30 kJ mol−1 for its heat of formation. Further dissociation of this species by the loss of CO took place very close to the calculated thermochemical threshold, confirming the formation of the cyclopentadienyl cation. The above result confirms the earlier estimated stability of this [C6,H5,O]+ isomer relative to those of the phenoxy and hydroxyphenyl cations." @default.
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- W2079854032 date "1997-11-01" @default.
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- W2079854032 title "The heat of formation of the [C6,H5,O]+ isomeric ion, protonated 6-oxafulvalene" @default.
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- W2079854032 doi "https://doi.org/10.1016/s0168-1176(97)00079-7" @default.
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