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- W2079854206 abstract "Solubilities of carvedilol (CVD) in binary mixtures of (ethanol + propylene glycol (PG)) at 298.2, 303.2, 308.2, and 313.2 K are reported. The modified versions of the van’t Hoff and Gibbs equations were used to calculate the thermodynamic properties (enthalpy (ΔH°), entropy (ΔS°), and Gibbs energy (ΔG°) standard changes of solutions) for CVD dissolved in (ethanol (1) + PG (2)) mixtures from the solubility data. The solubility data of CVD in (ethanol (1) + PG (2)) at different temperatures were correlated using different mathematical models, i.e., the Jouyban–Acree model, a combination of the Jouyban–Acree model with the van’t Hoff model, and two modified versions of the Jouyban–Acree model. Solubility data of seven drugs in (ethanol (1) + PG (2)) at different temperatures were used to develop a quantitative structure–property relationship model for predicting solubility in solvent mixtures. In addition, enthalpy–entropy compensation using ΔH° vs ΔG° and ΔH° vs TΔS° which explains the mechanism of cosolvency at different temperatures was discussed." @default.
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- W2079854206 date "2013-11-13" @default.
- W2079854206 modified "2023-10-10" @default.
- W2079854206 title "Solubility of Carvedilol in Ethanol + Propylene Glycol Mixtures at Various Temperatures" @default.
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- W2079854206 doi "https://doi.org/10.1021/ie403054z" @default.
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