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- W2079870144 abstract "Einkristalle von Ba2Cd3(VO4)2(V2O7) wurden durch Kristallisation aus einer Schmelze von BaCO3, CdO und V2O5 dargestellt. Sie zeigen orthorhombische Symmetrie, Raumgruppe DP212121 mit a = 7,206(2), b = 9,978(1), c = 19,617(3) Å, Z = 4. Die Kristallstruktur zeichnet sich durch VO4-Tetraeder, V2O7-Tetraederdoppel, CdO6-Oktaeder, BaO12− und BaO9−Polyeder und für Cd unübliche tetragonale Pyramiden aus. Die beobachteten [CdO4]-Zick-zack-Ketten werden durch VO4−Tetraeder, V2O7-Tetraederdoppel und CdO5−Pyramiden unter Ausbildung einer längs [100] orientierten Tunnelstruktur vernetzt. Die Tunnel sind mit Ba2+ aufgefüllt. Cadmium in Square Pyramids of Oxygen in the Barium Cadmium Oxovanadate: Ba2Cd3(VO4)2(V2O7) Single crystals of Ba2Cd3(VO4)2(V2O7) have been prepared by crystallization of a melt of BaCO3, CdO and V2O5. It shows orthorhombic symmetry, space group DP212121, a = 7.206(2), b = 9.978(1), c = 19.617(3) Å, Z = 4. The crystal structure is characterized by (VO4)3− and (V2O7)4− groups, CdO6 octahedra, BaO12 and BaO9 polyhedra and with respect to Cd containing oxides unusual square pyramids of O2− around Cd2+. The observed [CdO4] zickzack chains are connected by VO4 tetrahedra, V2O7 double tetrahedra and CdO5 pyramids, forming a tunnel structure along [100]. The tunnels are filled by barium." @default.
- W2079870144 created "2016-06-24" @default.
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- W2079870144 date "1997-07-01" @default.
- W2079870144 modified "2023-10-16" @default.
- W2079870144 title "Cadmium in tetragonal pyramidaler Koordination im Barium-Cadmium-Oxovanadat: Ba2Cd3(VO4)2(V2O7)" @default.
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- W2079870144 doi "https://doi.org/10.1002/zaac.19976230709" @default.
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