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• W2079873353 abstract "Possible domain patterns are developed for (001) oriented (pseudocubic indexing) epitaxial rhombohedral perovskite ferroelectric (FR) films. We assume that the films are grown above their Curie temperature (TC) in a cubic paraelectric (PC) state. The rhombohedral distortion consists of a “stretch” along one of the four 〈111〉 crystallographic directions of the cubic perovskite unit cell. Domain pattern formation is concurrent with the PC→FR transformation on cooling from the growth temperature. The domain patterns form to minimize elastic energy in the film, at the energetic expense of both forming domain boundaries and developing local stresses in the substrate. Eight possible domains may form, half of which are related by inversion, thus leading to four mechanically distinct variants. The possible domain walls are determined by mechanical and charge compatibility and follow closely from the analysis of Fousek and Janovec [J. Appl. Phys. 40, 135 (1969)]. Domain patterns may develop with either {100} or {1..." @default.
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• W2079873353 date "1998-03-01" @default.
• W2079873353 modified "2023-10-13" @default.
• W2079873353 title "Domain patterns in epitaxial rhombohedral ferroelectric films. I. Geometry and experiments" @default.
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• W2079873353 doi "https://doi.org/10.1063/1.366632" @default.
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