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- W2079874541 abstract "The composition dependences of molar volume and elastic constants were investigated for sodium and potassium germanate glasses of composition xR2O·GeO2 (O < x < 0.65 in the sodium-glasses and O < x < 0.75 in the potassium-ones). The variation of the molar volume could be approximated by straight lines crossing at 0.18 and 0.16 in x in the sodium- and potassium-glasses, respectively. At these compositions the elastic constants showed maxima. With reference to the structures of several alkali germanate crystals, it was concluded that the fraction of GeO6 units, N6, reaches a maximum at 0.18 in x in the sodium-glasses (15.6) mol.% Na2O) and at 0.16 in x in the potassium-glasses (13.8 mol.% K2O). It was also considered that N6 is not null at 0.5 but is null probably at 1.0 in x in the glasses. A network model of the germanate glasses was discussed." @default.
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- W2079874541 date "1985-03-01" @default.
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- W2079874541 title "The elastic constant and molar volume of sodium and potassium germanate glasses and the germanate anomaly" @default.
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- W2079874541 doi "https://doi.org/10.1016/0022-3093(85)90323-0" @default.
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