FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2079891410> ?p ?o ?g. }

• W2079891410 endingPage "661" @default.
• W2079891410 startingPage "655" @default.
• W2079891410 abstract "Rh+ ions in Rh–MFI are able to coordinate simultaneously three CO molecules at 293 K, the Rh+(CO)3 species formed being characterized by IR bands at 2181, 2118 and 2084 cm−1. During evacuation at 293 K the tricarbonyls are converted to Rh+(CO)2 geminal dicarbonyls (2114 and 2048 cm−1). The latter are quite stable and are decomposed at 673 K. Negligible amounts of Rh+–CO linear species (ca. 2114 cm−1) are produced during the decomposition of the dicarbonyls. At 100 K in the presence of gaseous CO the tricarbonyls can attach one more CO molecule. The proved frequencies of the Rh+(CO)4 species obtained are at 2164–2159 and 2112 cm−1. The results are explained by the high coordinative unsaturation of Rh+ in Rh–MFI. Experiments on CO–H2O coadsorption show formation of mixed Rh+(H2O)x(CO)2 complexes (2108 and 2040 cm−1) and also evidence that the relatively high CO frequencies of the gem-dicarbonyls are a result of the high coordinative unsaturation of Rh+ in Rh–MFI and the enhancement of the σ-component of the Rh+–CO bond as compared to Rh+(CO)2 species formed on oxide supports. NO replaces CO from the Rh+ cations producing Rh+(NO)2 dinitrosyls (1881 and 1786 cm−1). No evidence of mixed carbonyl–nitrosyl species has been found." @default.
• W2079891410 created "2016-06-24" @default.
• W2079891410 creator A5032166603 @default.
• W2079891410 creator A5040262289 @default.
• W2079891410 date "2002-12-19" @default.
• W2079891410 modified "2023-09-25" @default.
• W2079891410 title "Polycarbonyls of Rh+ formed after interaction of CO with Rh–MFI: an FTIR spectroscopic study" @default.
• W2079891410 cites W1503544507 @default.
• W2079891410 cites W1560165577 @default.
• W2079891410 cites W18339618 @default.
• W2079891410 cites W1972737180 @default.
• W2079891410 cites W1973496612 @default.
• W2079891410 cites W1973859129 @default.
• W2079891410 cites W1977216259 @default.
• W2079891410 cites W1978351410 @default.
• W2079891410 cites W1978938058 @default.
• W2079891410 cites W1980953390 @default.
• W2079891410 cites W1987582042 @default.
• W2079891410 cites W1988823524 @default.
• W2079891410 cites W1990398853 @default.
• W2079891410 cites W1992835571 @default.
• W2079891410 cites W1993129372 @default.
• W2079891410 cites W1993688883 @default.
• W2079891410 cites W1997367786 @default.
• W2079891410 cites W1997410182 @default.
• W2079891410 cites W1998703709 @default.
• W2079891410 cites W2005902780 @default.
• W2079891410 cites W2008530238 @default.
• W2079891410 cites W2021725917 @default.
• W2079891410 cites W2033963021 @default.
• W2079891410 cites W2035259876 @default.
• W2079891410 cites W2038028766 @default.
• W2079891410 cites W2039570197 @default.
• W2079891410 cites W2043238400 @default.
• W2079891410 cites W2045982179 @default.
• W2079891410 cites W2048941450 @default.
• W2079891410 cites W2060988811 @default.
• W2079891410 cites W2064152412 @default.
• W2079891410 cites W2066487880 @default.
• W2079891410 cites W2076295992 @default.
• W2079891410 cites W2081823680 @default.
• W2079891410 cites W2081825889 @default.
• W2079891410 cites W2084184810 @default.
• W2079891410 cites W2086766104 @default.
• W2079891410 cites W2088802558 @default.
• W2079891410 cites W2089072035 @default.
• W2079891410 cites W2089854206 @default.
• W2079891410 cites W2092712289 @default.
• W2079891410 cites W2095332637 @default.
• W2079891410 cites W2116390039 @default.
• W2079891410 cites W2140542156 @default.
• W2079891410 cites W2212136337 @default.
• W2079891410 cites W235615499 @default.
• W2079891410 cites W299670270 @default.
• W2079891410 cites W3137327931 @default.
• W2079891410 doi "https://doi.org/10.1039/b210711b" @default.
• W2079891410 hasPublicationYear "2002" @default.
• W2079891410 type Work @default.
• W2079891410 sameAs 2079891410 @default.
• W2079891410 citedByCount "39" @default.
• W2079891410 countsByYear W20798914102012 @default.
• W2079891410 countsByYear W20798914102014 @default.
• W2079891410 countsByYear W20798914102015 @default.
• W2079891410 countsByYear W20798914102016 @default.
• W2079891410 countsByYear W20798914102017 @default.
• W2079891410 countsByYear W20798914102019 @default.
• W2079891410 countsByYear W20798914102020 @default.
• W2079891410 countsByYear W20798914102021 @default.
• W2079891410 countsByYear W20798914102022 @default.
• W2079891410 countsByYear W20798914102023 @default.
• W2079891410 crossrefType "journal-article" @default.
• W2079891410 hasAuthorship W2079891410A5032166603 @default.
• W2079891410 hasAuthorship W2079891410A5040262289 @default.
• W2079891410 hasConcept C121332964 @default.
• W2079891410 hasConcept C124681953 @default.
• W2079891410 hasConcept C160892712 @default.
• W2079891410 hasConcept C161790260 @default.
• W2079891410 hasConcept C178790620 @default.
• W2079891410 hasConcept C179104552 @default.
• W2079891410 hasConcept C185592680 @default.
• W2079891410 hasConcept C201268389 @default.
• W2079891410 hasConcept C2779758233 @default.
• W2079891410 hasConcept C32909587 @default.
• W2079891410 hasConcept C62520636 @default.
• W2079891410 hasConcept C71240020 @default.
• W2079891410 hasConcept C8010536 @default.
• W2079891410 hasConceptScore W2079891410C121332964 @default.
• W2079891410 hasConceptScore W2079891410C124681953 @default.
• W2079891410 hasConceptScore W2079891410C160892712 @default.
• W2079891410 hasConceptScore W2079891410C161790260 @default.
• W2079891410 hasConceptScore W2079891410C178790620 @default.
• W2079891410 hasConceptScore W2079891410C179104552 @default.
• W2079891410 hasConceptScore W2079891410C185592680 @default.
• W2079891410 hasConceptScore W2079891410C201268389 @default.
• W2079891410 hasConceptScore W2079891410C2779758233 @default.
• W2079891410 hasConceptScore W2079891410C32909587 @default.
• W2079891410 hasConceptScore W2079891410C62520636 @default.
• W2079891410 hasConceptScore W2079891410C71240020 @default.

• next