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- W2079894123 abstract "Rhodium(I) complexes of Rh(acac)(CO)(L) type (where L = P(OMe)3, P(OEt)3, P(OPh)3, P(O-o-MeC6H4)3, PPh3, P(p-MeC6H4)3, PMePh2, AsPh3) react with alcohols and formaldehyde. In absence of free ligand (L) only carbonyl complexes of formula Rh4(CO)8(L)4 (or Rh4(CO)12-x(L)x) are formed. Reaction of Rh(acac)(CO)(PPh3) with methanol or formaldehyde in the presence of free PPh3 leads to the formation of HRh(CO)(PPh3)3 only." @default.
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- W2079894123 date "1992-05-01" @default.
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- W2079894123 title "Rhodium hydride (HRh(CO)(PPh3)3) and rhodium carbonyl (Rh4(CO)8L4) complexes obtained by reaction of Rh(acac)(CO)(L) type complexes with methanol and formaldehyde" @default.
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- W2079894123 doi "https://doi.org/10.1016/0022-328x(92)83254-f" @default.
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