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• W2079902275 startingPage "1458" @default.
• W2079902275 abstract "Reaction of cadmium perchlorate and the prototypical linear bridging ligand 4,4’-bipyridine (4,4’-bipy) in an ethanol/water mixture affords the one-dimensional coordination polymer, [{Cd(m-4,4’-bipy)(4,4’-bipy)2(H2O)2}(ClO4)2 × 2 4,4’-bipy × 4.5 H2O]n (1). The Cd2+ ions adopt an octahedral coordination sphere and are joined into linear chains by 4,4’-bipy via two trans coordination sites. The remaining two trans sites in the equatorial plane carry terminally monodentate-bound 4,4’-bipy ligands, resulting in a molecular antenna arrangement. The two axial sites of each Cd2+ ion are occupied by aqua ligands. Compound 1 crystallizes in the non-centrosymmetric, monoclinic space group C2 with three similar, crystallographically independent, cationic coordination polymer strands in the unit cell, which essentially differ only in the conformations of the 4,4’-bipyridyl ligands. Consistent with the similarity of the local coordination environments of the three independent Cd atoms in the structure, 113Cd MAS NMR spectroscopy reveals a single resonance line at 89 ppm." @default.
• W2079902275 created "2016-06-24" @default.
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• W2079902275 date "2011-09-05" @default.
• W2079902275 modified "2023-10-16" @default.
• W2079902275 title "A Molecular Antenna Coordination Polymer from Cadmium(II) and 4,4’-Bipyridine Featuring Three Distinct Polymer Strands in the Crystal" @default.
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• W2079902275 doi "https://doi.org/10.3390/polym3031458" @default.
• W2079902275 hasPublicationYear "2011" @default.
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