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- W2079920611 abstract "Die gegenüber ionischen Additionen an Aldehyde sehr inerten Aryl- und 1-Alkenylboronsäuren reagieren in wäßriger Phase bei 80–95°C in Gegenwart eines [Rh(acac)(CO)2]-Diphosphan-Katalysators zu sekundären Alkoholen [Gl. (a)]. Ein entscheidender Schritt im Katalysecyclus ist die Transmetallierung zwischen dem Borreagens und dem Rhodiumkomplex. Ln = Diphosphan, z. B. 1,1′-Bis(diphenylphosphanyl)ferrocen; R = Aryl, 1-Alkenyl; R′ = Alkyl, Aryl; acac = Acetylacetonat." @default.
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- W2079920611 date "1998-12-04" @default.
- W2079920611 modified "2023-10-16" @default.
- W2079920611 title "Rhodiumkatalysierte Addition von Organoboronsäuren an Aldehyde" @default.
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- W2079920611 doi "https://doi.org/10.1002/(sici)1521-3757(19981204)110:23<3475::aid-ange3475>3.0.co;2-w" @default.
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