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- W2079969050 abstract "Exceptionally high selectivity for cesium ions (α(Cs/Na) > 33000) is displayed by calix[4]arenecrowns-6 in the 1,3-alternate conformation. They also remove 137Cs quantitatively (>96%) from radioactive waste that is 1 M in HNO3. The complexation properties result from the simultaneous operation of several effects: the size of the crown ether ring, the polarity of the calix conformation, and the strength of the cation/π-electron interactions. The latter interaction was evident in the X-ray crystal structure of the cesium complex (shown on the right)." @default.
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- W2079969050 date "1994-08-02" @default.
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- W2079969050 title "1,3-Dialkoxycalix[4]arenecrowns-6 in 1,3-Alternate Conformation: Cesium-Selective Ligands that Exploit Cation-Arene Interactions" @default.
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- W2079969050 doi "https://doi.org/10.1002/anie.199415061" @default.
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