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• W2079969182 abstract "The closed mathematical model of a well-mixed batch crystallizer has been presented. This model takes into consideration crystals growth rate fluctuations producing an increased spread of crystal sizes. The numerical methods for solving partial integro-differential system of this model equations are proposed for the cases of when growth rate is expressible as product of supersaturation and size functions. Simultaneous population and mass balance equations have been calculated together with power law kinetics of nucleation and growth to determine crystal-size distribution functions (CSD), variation coefficients (CV), produced crystal sizes and numbers. The case of size-dependent crystal growth determined by sequential processes of diffusion and surface reaction is also investigated. The computer results are presented in the dimensionless form as functions on both diffusion and fluctuation Peclet numbers and dimensionless cooling rate. In particular, it has been established that the CV of weight CSD increases approximately twice due to fluctuations and becomes close to 40%; the CV also increases owing to the decrease of cooling rate and approaches 28%. Some formulae are suggested for predicting the kinetics of crystallization (or precipitation) and determining the kinetic parameters of crystals growth and nucleation." @default.
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• W2079969182 date "1981-01-01" @default.
• W2079969182 modified "2023-10-16" @default.
• W2079969182 title "Simulation of batch crystallization" @default.
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• W2079969182 doi "https://doi.org/10.1016/0009-2509(81)80089-9" @default.
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