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- W2079976418 abstract "The formation of a solid by the reaction of small gaseous molecules during a CVD or CVT experiment is a highly complicated process. In the case of the combustion of silicon(IV) chloride in oxygen, which leads to solid silicon dioxide, hundreds of intermediate chlorosiloxanes have been detected. On the basis of their compositions, structures, and stabilities, growth mechanisms of Si–O networks can be derived. The stepwise formation of solid SiO2 can be described in terms of three basic reactions: (i) formation of highly reactive O=SiCl2, (ii) insertion of O=SiCl2 into an Si–Cl bond, and (iii) thermally induced elimination of SiCl4 from the resulting chlorosiloxanes." @default.
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- W2079976418 date "2000-06-01" @default.
- W2079976418 modified "2023-09-23" @default.
- W2079976418 title "The Formation of a Solid from the Reaction SiCl4(g) + O2(g) → SiO2(s) + 2Cl2(g)" @default.
- W2079976418 doi "https://doi.org/10.1002/(sici)1099-0682(200006)2000:6<1127::aid-ejic1127>3.0.co;2-6" @default.
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