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- W2079979565 abstract "Michael addition of diethyl acetylaminomalonate to chalcone under Asymmetric Phase Transfer Catalysis without solvent has been successfully carried out in the presence of ephedrinium salts. Substituent effects on the benzyl moiety of the ammonium part of the catalyst revealed the importance of π-π attractive interactions between the catalyst and the electrophile on enantioselectivity. The best result (82% ee) was obtained with easy accessible (S) binaphthyl compound." @default.
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- W2079979565 date "1993-01-01" @default.
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- W2079979565 title "Asymmetric Michael reaction under PTC conditions without solvent Importance of π interactions for the enantioselectivity" @default.
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- W2079979565 doi "https://doi.org/10.1016/0040-4039(93)85105-6" @default.
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