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- W2080003148 abstract "A synthetic tris-(bis-(aminomethyl)pyridine) receptor was prepared in excellent yields via reversible imine condensation strategy. Catalytic activity in Henry reactions of the corresponding copper(II) complex was studied. Capitalizing on previous works by Anslyn with related receptors, the dramatic increase in basicity induced by this type of complex on diketo-derivatives was used to perform a nucleophilic addition of a deprotonated substrate onto an electrophile within the cavity. Hence, a Lewis acid stabilized nitronate was reacted with various aldehydes. A notable preference for small reactants easily accommodated in the cavity over encumbered ones was observed, thus representing an example of substrate-selectivity." @default.
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- W2080003148 date "2012-01-01" @default.
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- W2080003148 title "Toward reactant encapsulation for substrate-selectivity" @default.
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- W2080003148 doi "https://doi.org/10.1016/j.tetlet.2011.11.078" @default.
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